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- W2090936768 abstract "Frequency dependent electrical conductivity (σ′) of mechanochemically synthesized amorphous fast ion conductors (FICs) xAg2S–Sb2S3 (x=70, 80, 85) is investigated in the frequency range 5 Hz–13 MHz and temperature range 95–385 K. While the universal dynamic response (UDR) model, σ′ (ω)=σdc(T)+A(T)ωn, does reproduce the shape of σ′ (ω) spectra, the σdc(T) and A(T) show anomalous characteristics. Both exhibit two distinct Arrhenius regions, a low temperature region with a lower value of activation energy (E) and a high temperature region with higher value of activation energy. Further the frequency exponent n is a (decreasing) function of temperature, decreasing slowly at lower temperatures but more rapidly at higher temperatures. The correlation Eac=(1−n)Edc appears satisfactory in the low temperature region but unsatisfactory at higher temperatures. The isochronal representation of ac conductivity, σ′ vs. 1000/T at different frequencies, reveals the existence of a third regime, which is currently under active discussion and is known as superlinear power law (SLPL)." @default.
- W2090936768 created "2016-06-24" @default.
- W2090936768 creator A5004394150 @default.
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- W2090936768 date "2005-04-29" @default.
- W2090936768 modified "2023-09-26" @default.
- W2090936768 title "Ion dynamics in mechanochemically synthesized amorphous fast ionic conductor AgS–SbS" @default.
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- W2090936768 doi "https://doi.org/10.1016/j.ssi.2005.01.005" @default.
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