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• W2090947529 abstract "The system Br/Pt(110) is studied by scanning tunneling microscopy, low energy electron diVraction, angle resolved photoemission and self-consistent ab initio calculations. Bromine is molecularly adsorbed at 300 K, but dissociates at T>400 K. The Br atoms adsorb substitutionally and form quasi-one-dimensional (1D) PtMBrMPt chains. The 1D character of the chains gives rise to a charge density wave ground state, which can be triggered by surface doping. A Fermi surface yielding an appropriate nesting vector is identified by photoemission. Furthermore, a Br-induced lowering of Pt d-bands is observed, which accounts in part for the halogen-induced poisoning. The PtMBr bond is shown to be essentially covalent, ruling out electrostatic poisoning mechanisms. © 2000 Elsevier Science B.V. All rights reserved." @default.
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• W2090947529 date "2000-05-01" @default.
• W2090947529 modified "2023-09-27" @default.
• W2090947529 title "Electronic structure of a catalyst poison: Br/Pt(110)" @default.
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• W2090947529 doi "https://doi.org/10.1016/s0039-6028(00)00074-1" @default.
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