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- W2090968675 abstract "1, 3-Diene (la—d) lassen sich kathodisch mit aktivierten Olefinen, z. B. α,β-ungesättigten Estern und Ketonen (2a—g), zu den δ,ϵ-ungesättigten Estern und Ketonen (3, 4, 7, 9, 17—21) gemischt hydrodimerisieren. Die Reaktion läuft nach einem Radikalkupplungsmechanismus gleichzeitig auf der Kathode gebildeter Radikalanionen beider Reaktionspartner ab. Voraussetzung für das Gelingen ist eine Differenz der Halbwellenpotentiale der Synthesebausteine von höchstens 0.6 Volt. Concerning the Cathodical Addition of Activated Olefins to 1,3-Dienes. A New Synthesis of δ,ϵ-Unsaturated Carbonic Acid Esters and Ketones Conjugated olefins (la—d) are cathodically combined with activated olefins such as α,β-unsaturated esters and ketones (2a—g) by mixed hydrodimerisation giving δ,ϵ-unsaturated esters and ketones (3, 4, 7, 9, 17—21). The reaction follows a radical coupling mechanism involving radical ions of both reaction species generated upon the electrode surface at the same time. The synthesis will only succed if the building blocs do not differ more than 0.6 volt in their half wave potentials." @default.
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- W2090968675 date "1979-08-01" @default.
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- W2090968675 title "Zur kathodischen Addition von aktivierten Olefinen an 1,3-Diene. Ein neuer Weg zu δ,ε-ungesättigten Carbonsäureestern und Ketonen" @default.
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- W2090968675 doi "https://doi.org/10.1002/cber.19791120804" @default.
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