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- W2090969006 abstract "The kinetics of oxidation of benzyl alcohol and substituted benzyl alcohols by sodium N-chloro-p-toluenesulfonamide (chloramine-T, CAT) in HClO4 (0.1–1 mol/dm3) containing Cl− ions, over the temperature range of 30–50°C have been studied. The reaction is of first order each with respect to alcohol and oxidant. The fractional order dependence of the rate on the concentrations of H+ and Cl− suggests a complex formation between RNCl− and HCl. In higher acidic chloride solution the rate of reaction is proportional to the concentrations of both H+ and Cl7hyphen;. The observed solvent isotope effect (k/k) is 1.43 at 30°C. The reaction constant (p = −1.66) and thermodynamic parameters are evaluated. Rate expressions and probable mechanisms for the observed kinetics have been suggested." @default.
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- W2090969006 date "1980-11-01" @default.
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- W2090969006 title "Kinetics of oxidation of benzyl alcohol by sodiumN-chloro-p-toluenesulfonamide" @default.
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- W2090969006 doi "https://doi.org/10.1002/kin.550121105" @default.
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