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• W2090978715 endingPage "79" @default.
• W2090978715 startingPage "75" @default.
• W2090978715 abstract "Abstract Poly( cis‐ cyclooctene) is synthesized via ring‐opening metathesis polymerization in the presence of a chain‐transfer agent and quantitatively hydrobrominated. Subsequent graft polymerization of tert ‐butyl acrylate ( t BA) via Cu‐catalyzed atom transfer radical polymerization (ATRP) from the non‐activated secondary alkyl bromide moieties finally results in PE‐ g ‐P t BA copolymer brushes. By varying the reaction conditions, a series of well‐defined graft copolymers with different graft densities and graft lengths are prepared. The maximum extent of grafting in terms of bromoalkyl groups involved is approximately 80 mol%. DSC measurements on the obtained graft copolymers reveal a decrease in T m with increasing grafting density." @default.
• W2090978715 created "2016-06-24" @default.
• W2090978715 creator A5004249562 @default.
• W2090978715 creator A5011721889 @default.
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• W2090978715 date "2011-11-18" @default.
• W2090978715 modified "2023-10-10" @default.
• W2090978715 title "Functional Polyolefins: Poly(ethylene)-<i>graft</i> -Poly(<i>tert</i> -butyl acrylate) via Atom Transfer Radical Polymerization From a Polybrominated Alkane" @default.
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• W2090978715 doi "https://doi.org/10.1002/marc.201100521" @default.
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