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• W2090980575 abstract "A polyfunctional arylacetylenic monomer, 1,2,4-tris(phenylethynyl)benzene, thermally polymerizes by a free-radical mechanism to a highly crosslinked structure of interest as a precursor matrix for carbon/carbon composites. The polymerization reaction was characterized by Fourier transform infra-red spectroscopy and differential scanning calorimetry (d.s.c.). The disappearance of the acetylenic stretching band at 2212 cm−1 was used successfully to monitor the cure reaction. The cure reaction follows first-order kinetics with an overall activation energy of 135 kJ mol−1. Dynamic d.s.c. analysis carried out to estimate the activation energy of the cure reaction yields a value of 137 kJ mol−1." @default.
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• W2090980575 date "1995-03-01" @default.
• W2090980575 modified "2023-09-23" @default.
• W2090980575 title "Cure kinetics of a multisubstituted acetylenic monomer" @default.
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• W2090980575 doi "https://doi.org/10.1016/0032-3861(95)95924-p" @default.
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