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- W2090983029 abstract "It has been shown (i) that a mixture of dichlorobis(triphenylphosphine)platinum(II) and tin(II) chloride acts as a homogeneous catalyst for the hydrogenation of a number of polyolefinic compounds. This catalyst appeared to be unique in that, unlike similar catalysts, it does not catalyze hydrogenation of these olefins beyond the monoene stage. This behavior has been explained by proposing that the catalyst must first form a labile intermediate with a conjugated diene species. Since this earlier publication, we have made a detailed study of a series of simple dienes and monoenes. These have shown several important features about the mechanism of hydrogenation which conflict with some previously held concepts. Table 1 lists the results of hydrogenation experiments for a series of simple monoenes. Hydrogenation is most effective for olefins having terminal double bonds; removal of the double bond from a terminal position significantly reduces the amount of hydrogenation." @default.
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- W2090983029 date "1968-08-01" @default.
- W2090983029 modified "2023-09-29" @default.
- W2090983029 title "Homogeneous catalytic hydrogenation and isomerization of olefins with dichlorobis (triphenylphosphine) platinum(II)-tin(II) chloride catalyst" @default.
- W2090983029 cites W2313436119 @default.
- W2090983029 doi "https://doi.org/10.1016/0020-1650(68)80034-0" @default.
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