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• W2091002729 abstract "Meyer−Schuster rearrangements of propargylic alcohols take place readily at room temperature in toluene with 1−2 mol % PPh3AuNTf2, in the presence of 0.2 equiv of 4-methoxyphenylboronic acid or 1 equiv of methanol. Good to excellent yields of enones can be obtained from secondary and tertiary alcohols, with high selectivity for the E-alkene in most cases. A one-pot procedure for the conversion of primary propargylic alcohols into β-arylketones was also developed, via Meyer-Schuster rearrangement followed by Pd-catalayzed addition of a boronic acid." @default.
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• W2091002729 date "2011-01-25" @default.
• W2091002729 modified "2023-10-07" @default.
• W2091002729 title "A General Procedure for the Synthesis of Enones via Gold-Catalyzed Meyer−Schuster Rearrangement of Propargylic Alcohols at Room Temperature" @default.
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• W2091002729 doi "https://doi.org/10.1021/jo102263t" @default.
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