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- W2091016078 abstract "Abstract An X-ray diffraction study has confirmed that reaction of [Ru5C(CO)15] (1) with an excess pyridine gives an equimolar mixture of two isomers of [HRu5C(CO)14− (C5H4N)] (2a and 2b) that differ only in the orientation of a bridging ligand, along with a third minor product [HRu5C(CO)13(C5H4N)(C5H5N)] (3); 2a and 2b undergo quantitative thermal decarbonylation to give the same unstable product [HRu5C(CO)13(C5H4N)] (4), which can be recarbonylated quantitatively under mild conditions to regenerate equal proportions of the isomers 2a and 2b." @default.
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- W2091016078 date "1989-12-01" @default.
- W2091016078 modified "2023-10-03" @default.
- W2091016078 title "Isomeric clusters differing only in the orientation of a bidentate ligand; synthesis and crystal structures of two isomers of [HRu5C(CO)14(C5H4N)]" @default.
- W2091016078 cites W2012871380 @default.
- W2091016078 doi "https://doi.org/10.1016/0022-328x(89)80041-5" @default.
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