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- W2091062193 abstract "Mole fractions of the two surface-active components of aqueous mixtures of anionic and cationic surfactants at aqueous solution-air, -Teflon, and -Parafilm interfaces, calculated by two nonideal solution treatments, are compared to those obtained by use of the Gibbs adsorption equation. The treatment based upon the assumption that the ratio of partial molar areas of the two surfactants in the mixed monolayer equals the ratio of the molar monolayer areas of the two individual surfactants at the same interfacial tension (treatment “R”) gives mole fraction values in close agreement with these obtained by use of the Gibbs equation. The treatment based upon the assumption that the area occupied by the surfactant in the mixed monolayer is not significantly different from that in a monolayer of the individual (treatment “E”) gives values that deviate more. Molecular interaction parameters for mixed monolayer formation at the various interfaces, calculated by treatment “R,” are essentially constant with change in either the ratio of the two surfactants in the aqueous phase or the interfacial tension; values from treatment “E” varied with the interfacial tension and the degree of change in the surfactant area at the interface. When interaction between the two surfactants in the mixed monolayer is relatively weak, the two treatments yield essentially the same interfacial mole fraction and interaction parameter values." @default.
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- W2091062193 title "Surface concentrations and molecule interactions in cationic-anionic mixed monolayers at various interfaces" @default.
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