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- W2091072535 abstract "The infra-red spectrum of perylene single crystals has been measured in polarized light between 4000 and 400 cm−1. The oriented gas model predicts for the infra-red active modes (D2h symmetry) the following polarization pattern: B3u band absent in the (001) crystal plane spectrum; B2u bands stronger with light polarized along the b axis; B1u bands stronger with light polarized along the a crystal axis. The observed band dichroism for mostly of the bands occurring in the spectrum agrees nicely with these predictions. The vibrational assignment of these bands is discussed. In addition some other bands occur in the spectrum which show a type of polarization incoherent with the oriented gas model predictions. Some of these are absent in solution and are interpreted as inactive fundamentals made active by the factor group symmetry. The other are explained as due to a distortion of the D2h symmetry due to the interaction between the over-crowded hydrogen atoms." @default.
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- W2091072535 date "1965-08-01" @default.
- W2091072535 modified "2023-09-26" @default.
- W2091072535 title "The vibrational spectrum of perylene" @default.
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- W2091072535 doi "https://doi.org/10.1016/0371-1951(65)80050-9" @default.
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