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- W2091130461 abstract "Rates were obtained for the pyrolysis of tosyl arenecarboxaldehyde hydrazones (1–5), and mesyl benzaldoxime (6). The substituted tosyl sulphonamides (TsHNN=CHAr: 1–5) and the mesylate (6) gave in a novel pyrolytic reaction the following Arrhenius log A/s−1 and Ea/kJ mol−1 values, respectively: 12.70 and 157.7 (1, ArC6H5), 12.29 and 152.6 (2, p-NO2C6H4), 11.85 and 148.2 (3, m-NO2C6H4), 12.17 and 152.0 (4, p-ClC6H4), 11.01 and 140.8 (5, p-CH3OC6H4), and 12.96 and 109.9 for (6). Tosyl benzaldoxime (7) was also studied. The reactions yielded cyanoarenes together with sulphonic acids from 6 and 7, and p-methylbenzenesulphonamide from compounds 1–5." @default.
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- W2091130461 date "1998-04-01" @default.
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- W2091130461 title "Kinetics and mechanism of pyrolysis of sulphonyl hydrazones and oximes. Part 1. Contribution to reactivity from hydrazone HNN and oxime ON bond polarity" @default.
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- W2091130461 doi "https://doi.org/10.1016/s0040-4020(98)00179-3" @default.
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