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- W2091148696 abstract "Abstract Low‐temperature 1 H, 13 C, and 119 Sn NMR spectroscopic techniques were used to probe the nature of cuprates derived from Me 3 SnLi, CuCN, or CuBr · Me 2 S. In THF, addition of Me 3 SnLi and CuX (X = Br or CN) gives aggregated [Me 3 SnCu · LiX] n . When the ratio of stannyl anion to cuprous cation is 2 : 1, mixtures of (Me 3 Sn) 3 Cu 2 Li, (Me 3 Sn) 2 CuLi · LiX, and (Me 3 Sn) 3 CuLi 2 are formed. This behavior is unlike either homo trialkylsilycyanocuprates, which form (R 3 Si) 2 Cu(CN)Li 2 at 2 : 1 ratios of silyl anion to cuprous ion, or mixed trialkylstannyl‐ or trialkylsilyl‐cuprates, which exist as (R 3 M)Cu(R′)(CN)Li 2 (M = Si or Sn and R′ = Me or Bu). (R 3 Sn) 3 CuLi 2 is the major species when the stannyl anion to cuprous cation ratio reaches 3 : 1. On the other hand, the analogous magnesium cuprates are discrete species in solution and possess differential reactivity." @default.
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- W2091148696 title "(Trialkylstannyl)cuprates: A spectroscopic and chemical investigation" @default.
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- W2091148696 doi "https://doi.org/10.1002/hc.520050503" @default.
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