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• W2091151200 abstract "Troglitazone (CS-045) is a new oral antidiabetic drug reported to be effective in insulin-resistant diabetes and to show antihypertensive effects. Photooxidation of troglitazone gave the quinone and quinone epoxide as the major final stable products. An intermediate observed by NMR spectroscopy was shown to be the hydroperoxydi-enone, which is moderately stable at room temperature. The rate constant of singlet oxygen quenching by troglitazone is 2.14 × 108M−1s−1 and the reaction rate constant in acetone-d, is 8.64 × 10, M−1 s−1. Only the chroman ring of troglitazone reacts with and quenches singlet oxygen significantly, and its reactivity and products are analogous to those of a-tocopherol. The reactivity of CS-045 toward singlet oxygen is much larger than that of the related compounds lacking the chroman ring." @default.
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• W2091151200 date "1996-05-01" @default.
• W2091151200 modified "2023-09-23" @default.
• W2091151200 title "Photooxidation of Troglitazone, a New Antidiabetic Drug" @default.
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• W2091151200 doi "https://doi.org/10.1111/j.1751-1097.1996.tb05664.x" @default.
• W2091151200 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/8628753" @default.
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