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- W2091152017 abstract "Ruthenium monofluoride, RuF, has been detected using low-resolution laser-induced fluorescence (LIF) in the visible and near infrared spectral regions. A visible band, designated as [18.2]5.5−XΦ9∕24, has been recorded field-free and in the presence of a static electric field using high-resolution LIF spectroscopy. The r0 internuclear distances for the [18.2]5.5 and XΦ9∕24 states were determined to be 1.911 and 1.916Å, respectively. The vibrational interval ΔG1∕2 of 534(15)cm−1 for the XΦ9∕24 state was determined from the analysis of the dispersed LIF. The Stark shifts of the visible band were analyzed to produce permanent electric dipole moments of 1.97(8) and 5.34(7)D for the [18.2]5.5 and XΦ9∕24, states, respectively. The fluorine magnetic hyperfine structure associated with spectral features was analyzed. The hyperfine structure and dipole moments are interpreted using a molecular-orbital correlation model and compared with FeF and other ruthenium-containing molecules." @default.
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- W2091152017 date "2006-01-10" @default.
- W2091152017 modified "2023-10-16" @default.
- W2091152017 title "The permanent electric dipole moment and hyperfine interaction in ruthenium monoflouride (RuF)" @default.
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- W2091152017 doi "https://doi.org/10.1063/1.2145880" @default.
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