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- W2091161005 abstract "Monodisperse latexes show a first order phase transition from the disordered to the ordered state under certain conditions. In the present study, the osmotic pressure and the volume fraction are measured at the phase transition (melting) point by the use of sedimental equilibrium. At relatively high electrolyte concentration (around 10 −2 mol/l) of the medium, the pressure is very near the value of the Alder transition, though the volume fraction is less than 0.55 (the theoretical value for the melting point in the transition). At low electrolyte concentration (⋍10 −3 mol/l), the pressure is higher, showing the effect of the repulsive potential. At high concentration (5 × 10 −2 mol/l), the pressure is markedly depressed due to the effect of the van der Waals force or of the secondary minimum. The effect of the colloid interaction on the transition condition is that: 1) the inner part of the potential that is strongly repulsive does not influence the transition pressure but only works to increase the effective size of the particles; and 2) the pressure is affected only by the outer part of the potential." @default.
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- W2091161005 title "Pressure of disorder to order transition in monodisperse latex" @default.
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- W2091161005 doi "https://doi.org/10.1016/0001-8686(82)85018-5" @default.
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