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- W2091201227 abstract "High-resolution volumetric adsorption isotherms of ammonia-on-MgO(100) surfaces have been recorded over the temperature range 160--200 K (using powder prepared by a recently introduced process). Evidence is presented that indicates that multilayer formation is possible at $T>~173mathrm{K}$ (at least three layers). We have observed a series of layering transitions including a crossover from incomplete to complete wetting near the triple point of ammonia. The isothermal compressibility and isosteric heat of adsorption are determined. These data are compared with earlier results obtained for ammonia on graphite and used to describe the status of the film with regard to temperature and coverage. The importance of high-quality MgO substrates is discussed and areas for further study using structural methods are mentioned." @default.
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- W2091201227 date "1999-03-15" @default.
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- W2091201227 title "Wetting and adsorption of ammonia on magnesium oxide" @default.
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- W2091201227 doi "https://doi.org/10.1103/physrevb.59.8247" @default.
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