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• W2091202106 abstract "Three novel uranyl complexes with organic phosphine oxide ligands and bridging fluorides have been synthesised and structurally characterised. In [{UO2(μ-F)(TPPO)3}2][BF4]2 · nC6H14, 1, and [{UO2(-μF)(TBPO)3}2][BF4]2 2, (where TPPO and TBPO are triphenylphosphine oxide and tri-n-butylphosphine oxide, respectively) two {UO2}2+ moieties are bridged by two fluorides with three additional terminal PO donor ligands coordinated to each uranium centre. The dicationic complexes are both charge balanced by two uncoordinated tetrafluoroborate anions. In the related structure, [UO2(μ-F)(F)(DPPMO2)]2 · 2MeOH (3), terminal fluoride is also coordinated to both uranyl centres (where DPPMO2 = bis(diphenylphosphine oxide)methane). All three complexes were prepared during attempted syntheses of complexes with tetrafluoroborate directly coordinated to uranium. It is clear from these results that the fluorophilicity of {UO2}2+ causes the abstraction of fluoride from [BF4]−, with the weakly coordinating anion only present as a counter cation in 1 and 2, and absent completely in 3." @default.
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• W2091202106 date "2004-12-01" @default.
• W2091202106 modified "2023-10-17" @default.
• W2091202106 title "Synthesis, structural and spectroscopic characterisation of three di-μ-fluoro-bis[dioxouranyl] complexes" @default.
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• W2091202106 doi "https://doi.org/10.1016/j.poly.2004.09.010" @default.
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