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- W2091205855 abstract "tert-Butylperoxy radicals enriched with oxygen-17 react with phenyl tert-butyl nitrone to give α-tert-butylperoxybenzyl tert-butyl nitroxide with a N = 13.42 G, a H = 0.95 G, a o β = 2.9 G, g = 2.0064. The O-hfsc decreases with an increase in temperature while the H-hfsc increases with an increase in temperature. This radical is not stable above about 273 K and is replaced by α-tert-butoxybenzyl tert-butyl nitroxide, a N = 13.62 G, a H = 1.72 G, a o β = 5.05 G, g = 2.0064.Alkylperoxy radicals are also trapped by 2-methyl-2-nitrosopropane to give alkylperoxy tert-butyl nitroxide a N = 28.7 G, a o ROO = 4.6 G, g = 2.0056 while the epr parameters for alkoxy tert-butyl nitroxide are a N = 27.25 G, a o RO = 1.03 G, g = 2.0057." @default.
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- W2091205855 date "1978-01-15" @default.
- W2091205855 modified "2023-10-17" @default.
- W2091205855 title "Electron paramagnetic resonance spectra of the <i>tert</i>-butylperoxy and <i>tert</i>-butoxy adducts to phenyl <i>tert</i>-butyl nitrone and 2-methyl-2-nitrosopropane. Oxygen-17 hyperfine coupling constants" @default.
- W2091205855 doi "https://doi.org/10.1139/v78-028" @default.
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