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- W2091208864 abstract "The crystal and molecular structure of the title compound was determined from single crystal X-ray diffraction. The complex crystallizes in the monoclinic space group P21/c, with Z = 4. Lattice parameters are: a = 12.121(3), b = 8.556(2), c = 15.269(4) Å and β = 91.86(2)°. The structure was solved by Patterson and Fourier techniques and refined by least-squares to a final conventional R value of 0.079. The europium(III) ion is 10-coordinate, being bonded to three bidentate nitrate groups and to the four oxygen atoms of the crown ether. The EuO distances are in the range in the range 2.41–2.57 Å (average: 2.49(5) Å. The nitrate groups are planar with NO bond lengths between 1.21 and 1.29 Å. The coordination polyhedron of Eu(III) is discussed. The effective ionic radius of the 10-coordinate Eu(III) ion is 1.178 Å." @default.
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- W2091208864 date "1982-01-01" @default.
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- W2091208864 title "Crystal structure and emission spectrum of tris(nitrato)-1,4,7,10-tetraozacyclododecane-Europium(III)" @default.
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- W2091208864 doi "https://doi.org/10.1016/s0020-1693(00)87342-9" @default.
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