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- W2091210802 abstract "A general procedure is described whereby the tert-butyldimethylsilylation of unsymmetrical 1,2- and 1,3-diols via their dibutylstannanediyl derivatives occurs regiospecifically at the primary hydroxy group under neutral conditions; six-membered ring acetals (derived from 1,3-diols) are found to react in preference to five-membered ring acetals (derived from 1,2-diols), the reverse of stannanediyl-mediated acylation, tosylation and alkylation procedures, leading to kinetically controlled discrimination between the different primary hydroxy groups of polyol systems such as butane-1,2,4-triol and lactose." @default.
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- W2091210802 date "1994-01-01" @default.
- W2091210802 modified "2023-10-14" @default.
- W2091210802 title "Kinetically controlled regiospecific silylation of polyols via dibutylstannanediyl acetals" @default.
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- W2091210802 doi "https://doi.org/10.1039/c39940001373" @default.
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