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- W2091212156 abstract "Abstract The benzylidene acetals obtained by cleavage of the orthobenzoate moiety in myo ‐inositol 1,3,5‐orthobenzoate were used to prepare mono‐ as well as di‐deoxy inositol derivatives via their xanthates. The dideoxygenation is a result of intramolecular abstraction of the benzylidene acetal hydrogen and subsequent cleavage of the acetal ring. Such a cleavage does not take place in analogous acetals derived from other orthoesters. The 1,3‐acetals derived from myo ‐inositol 1,3,5‐orthoesters were also used to prepare neo ‐inositol and isomeric deoxy‐amino inositols. Most of the reactions in these synthetic sequences starting from myo ‐inositol give one product in each step. The results presented here show that myo ‐inositol 1,3,5‐orthobenzoate offers many advantages over other orthoesters for the synthesis of cyclitol derivatives from myo ‐inositol." @default.
- W2091212156 created "2016-06-24" @default.
- W2091212156 creator A5023881228 @default.
- W2091212156 creator A5064388887 @default.
- W2091212156 creator A5082111945 @default.
- W2091212156 date "2010-01-18" @default.
- W2091212156 modified "2023-09-23" @default.
- W2091212156 title "Intramolecular Hydrogen Abstraction in Radicals Derived from Inositol 1,3-Acetals: Efficient Access to Cyclitols" @default.
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- W2091212156 doi "https://doi.org/10.1002/ejoc.200901156" @default.
- W2091212156 hasPublicationYear "2010" @default.
- W2091212156 type Work @default.