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- W2091216949 abstract "The anomalous positions in the microwave spectrum of ammonia of the lines originating with the rotational levels $K=3$ are explained on the basis of a $K$-type splitting of these levels. The splitting is due to a fourth-order perturbation originating with the first-order correction terms to the moments of inertia, ${{I}_{mathrm{xx}}}^{(e)}={{I}_{mathrm{yy}}}^{(e)}$, and the first-order coriolis correction terms. The Pauli exclusion principle permits only one of the two components to be present. Thus in the lower vibration state when $J$ is even only the lower component of the levels $K=3$ is present, but when $J$ is odd only the upper component is permitted. Similarly, for the upper vibration state when $J$ is even only the upper component of the levels $K=3$ may exist while for $J$ odd only the lower component may exist. Since in this spectrum $ensuremath{Delta}J=ensuremath{Delta}K=0$, the lines originating in levels where $J$ is even will be displaced to shorter wave-lengths, while the lines originating in levels where $J$ is odd will be displaced to longer wave-lengths. The agreement between computed shifts and measured shifts is satisfactory." @default.
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- W2091216949 date "1947-12-01" @default.
- W2091216949 modified "2023-10-03" @default.
- W2091216949 title "Anomalous Values of Certain of the Fine Structure Lines in the Ammonia Microwave Spectrum" @default.
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- W2091216949 doi "https://doi.org/10.1103/physrev.72.1101" @default.
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