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- W2091217411 abstract "The structures of the Mg, Ca, Sr and Ba salts of 1-naphthoic acid are examined and compared with analogous structures of salts of benzoate derivatives. It is shown that catena -poly[[[diaquabis(1-naphthoato-κ O )magnesium(II)]-μ-aqua] dihydrate], {[Mg(C 11 H 7 O 2 ) 2 (H 2 O) 3 ]·2H 2 O} n , exists as a one-dimensional coordination polymer that propagates only through Mg—OH 2 —Mg interactions along the crystallographic b direction. In contrast with related benzoate salts, the naphthalene systems are large enough to prevent inorganic chain-to-chain interactions, and thus species with inorganic channels rather than layers are formed. The Ca, Sr and Ba salts all have metal centres that lie on a twofold axis ( Z ′ = 1 over 2) and all have the common name catena -poly[[diaquametal(II)]-bis(μ-1-naphthoato)-κ 3 O , O ′: O ;κ 3 O : O , O ′], [ M (C 11 H 7 O 2 ) 2 (H 2 O) 2 ] n , where M = Ca, Sr or Ba. The Ca and Sr salts are essentially isostructural, and all three species form one-dimensional coordination polymers through a carboxylate group that forms three M —O bonds. The polymeric chains propagate via c -glide planes and through M O M O four-membered rings. Again, inorganic channel structures are formed rather than layered structures, and the three structures are similar to those found for Ca and Sr salicylates and other substituted benzoates." @default.
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- W2091217411 date "2012-07-19" @default.
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- W2091217411 title "Alkaline earth metal salts of 1-naphthoic acid" @default.
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- W2091217411 doi "https://doi.org/10.1107/s0108270112030399" @default.
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