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- W2091225564 abstract "Near-IR data for a series of mixed-valence π-bond bridged and σ-bond bridged di-, tri-, and tetra-ferrocene derivatives suggests intervalence electron transfer (IT) exists in all of the π-bond bridged and some of the σ-bond bridged compounds. The compounds exhibiting the electron transfer transition include the mixed valence derivatives of 1,2-diferrocenylethene, 1,2-diferrocenyl-1,2-diphenylethene, azoferrocene, 1,1-diferrocenylethene, diferrocenyl ketone, ferricenyl(III)tris-ferrocenyl(II))borate zwitterion, triferrocenylphosphine oxide, diferrocenylphenylphosphine oxide and triferrocenylmethane. Compounds studied that do not exhibit the near-IR transition when oxidized are triferrocenylborane, triferrocenylphosphine, diferrocenylphenylphosphine and diferrocenylmethane. The near-IR transition in the π-bond bridged derivatives is attributed to a predominantly through-bond mechanism while the transition in the σ-bond bridged derivatives is attributed to a through-space mechanism. It is suggested that the presence of the IT band in the phosphine oxides while being absent in the phosphine derivatives may be due to a difference in the dp-π overlap of phosphorus and the cyclopentadiene rings in the two systems." @default.
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- W2091225564 date "1983-09-01" @default.
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- W2091225564 title "Near-IR spectroscopic studies of mixed-valence di-, tri-, and tetraferrocene derivatives" @default.
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- W2091225564 doi "https://doi.org/10.1016/s0022-328x(00)99241-6" @default.
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