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- W2091234714 abstract "Abstract Molybdenum is a good catalyst for epoxidation of olefins with t-butyl hydroperoxide (t-BuOOH). However, use of this system for oxidation of alcohols has seldom been reported. Therefore, the catalytic activity of substituted ammonium tetrabromooxomolybdate(V) for t-BuOOH oxidation was investigated. The type of substituted ammonium ion used as a counter cation became a dominant factor. The ion with no hydrogen on the nitrogen showed only oxidation of alcohol, but ions with hydrogen on the nitrogen exhibited epoxidation activity. The investigation of oxidation of alcohols and olefins with t-BuOOH in the presence of the molybdenum complexes with substituted ammonium ion as a counter cation is described and discussed." @default.
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- W2091234714 date "1986-01-01" @default.
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- W2091234714 title "Catalysis by tetrabromooxomolybdate(V) complex: Oxidation of olefins and alcohols with t-butyl hydroperoxide" @default.
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- W2091234714 doi "https://doi.org/10.1016/s0277-5387(00)84924-4" @default.
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