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• W2091245495 abstract "A new type of flow injection analysis (FIA) system combined with an extremely high temperature reactor, namely hydrothermal flow injection analysis (HT-FIA), has been successfully constructed for the first time. Fundamental characteristics of HT-FIA system, such as limit temperature, pressure, and flow rate, were examined as an analytical tool. To demonstrate the potential of HT-FIA, the catalytic activity of Ir(IV) for the degradation of a water-soluble porphyrin, 5,10,15,20-tetraphenyl-21H,23H-porphinetetrasulfonic acid (TPPS), was applied for the determination of trace amounts of Ir(IV). Although the indicator reaction is very slow at room temperature, HT-FIA system enables to accelerate the reaction. A linear calibration curve was acquired at 10−8 M level of Ir(IV) and the interferences of platinum group metal ions were examined. The detection limit of Ir(IV) was 5.8 × 10−9 M and a fairly high-throughput analysis, of which more than 30 samples can be analyzed within 80 min, was achieved." @default.
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• W2091245495 date "2011-06-01" @default.
• W2091245495 modified "2023-09-29" @default.
• W2091245495 title "Flow injection analysis combined with a hydrothermal flow reactor: Application to kinetic determination of trace amounts of iridium using a water-soluble porphyrin" @default.
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• W2091245495 doi "https://doi.org/10.1016/j.talanta.2011.02.038" @default.
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