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- W2091249039 abstract "Novel methodology for the diastereoselective synthesis of some branched functionalized homoallylic amine derivatives is described. The protocol starts with a 3,6-dihydrothiazine-1-oxide, which is readily obtained in a totally stereospecific manner by the hetero-Diels—Alder cycloaddition of an N-sulfinyl dienophile and a 1,3-diene. Various Grignard reagents have been added to these adducts to afford sulfoxide derivatives which have been manipulated stereoselectively via [2,3]- or [3,3]-sigmatropic rearrangements into branched homoallylic amines potentially useful for further synthetic transformations." @default.
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- W2091249039 date "1986-01-01" @default.
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- W2091249039 title "Diastereoselective synthesis of highly functionalized homoallylic amine derivatives via diels—alder adducts of N-sulfinyl dienophiles" @default.
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- W2091249039 doi "https://doi.org/10.1016/s0040-4020(01)90588-5" @default.
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