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- W2091256328 abstract "Polymers and copolymers of alkyl isocyanates have been prepared by the method of Shashoua and their properties have been investigated. All the polymers have a significant decomposition rate at 150°C but the copolymers of butyl isocyanate with ethyl isocyanate are somewhat more stable than is the butyl homopolymer. The copolymers generally show reduced crystallinity and, with high concentrations of ethyl isocyanate, substantially amorphous polymers have been prepared. Dynamic mechanical measurements give damping peaks with a fall in modulus in the temperature range of 50°–150°C but the peaks are broader and the decline in modulus less steep than for conventional vinyl polymers. Over the same temperature range the differential scanning calorimetry (d.s.c.) curves are nearly linear and show no observable discontinuity. In mechanical tests both modulus and yield stress correlate with the NCO/hydrocarbon composition ratio. The form of the stress-strain curve in tension is similar to those of cellulose derivatives. They do not show a maximum and uniform extension occurs." @default.
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- W2091256328 date "1978-04-01" @default.
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- W2091256328 title "Properties of nylon-1 polymers and copolymers in the solid state" @default.
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- W2091256328 doi "https://doi.org/10.1016/0032-3861(78)90242-2" @default.
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