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- W2091259364 abstract "Radical copolymerisation of styrene and Zn-5-(-4-acrylamidophenyl)-10,15,20-phenylporphyrin (Zn-ATPP) is reported. The copolymer is characterized using visible, IR, proton and 13C NMR spectroscopies as well as elemental analysis. In this polymer a nonnegligible amount of Zn-chlorin is present which is titrated using absorption coefficients of Zn-chlorin prepared as described in literature. Films of different polymers such as polystyrene, statistical polystyrene-co-polyvinylpyridine and a sequenced polymer, poly(vinyl-2-pyridine)-block-polystyrene containing the monomer or the radical copolymer are studied. Absorption and fluorescence spectra are studied in solution and in films and compared to the spectra of Zn tetraphenyl porphyrin (Zn-TPP). The energy transfer between porphyrin (P) and chlorin (C) are shown to be dependent on the polarity of the polymer matrix." @default.
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- W2091259364 date "1995-09-01" @default.
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- W2091259364 title "Study of energy transfer between porphyrin and chlorin grafted on polystyrene" @default.
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- W2091259364 doi "https://doi.org/10.1016/1381-5148(95)00056-l" @default.
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