Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091260306> ?p ?o ?g. }
- W2091260306 endingPage "394" @default.
- W2091260306 startingPage "381" @default.
- W2091260306 abstract "This short article focuses attention on two areas of thermochemical concern. The first is the problem of determining enthalpies of formation of free radicals from ion-based experiments. A signal lack of success has attended the determination of Δ H°f298 for the vinyl radical, a value which leads to the bond strength in ethene, a basic thermochemical quantity. In marked contrast the appearance energy method has provided very satisfactory data for alkyl, alkoxy and other radicals. The second area of concern is the significance of threshold appearance energies and the “temperature” of the product species. For dissociative ionization of diatomic molecules the zero Kelvin notation for the threshold products appears to be correct, but for metastable, polyatomic, odd-electron ions the foregoing is probably an oversimplification. Concluding remarks call for new experimental methods to identify and measure the thermochemistry of ion/molecule, ion/radical and H-bridged odd-electron ions." @default.
- W2091260306 created "2016-06-24" @default.
- W2091260306 creator A5019090382 @default.
- W2091260306 date "1992-09-01" @default.
- W2091260306 modified "2023-10-12" @default.
- W2091260306 title "The present state and utility of ion thermochemistry" @default.
- W2091260306 cites W1490648806 @default.
- W2091260306 cites W1964242079 @default.
- W2091260306 cites W1970727628 @default.
- W2091260306 cites W1973739954 @default.
- W2091260306 cites W1974887842 @default.
- W2091260306 cites W1977965271 @default.
- W2091260306 cites W1978215598 @default.
- W2091260306 cites W1981700173 @default.
- W2091260306 cites W1983620899 @default.
- W2091260306 cites W1984771000 @default.
- W2091260306 cites W1985884023 @default.
- W2091260306 cites W1986579082 @default.
- W2091260306 cites W1988307617 @default.
- W2091260306 cites W1990108848 @default.
- W2091260306 cites W1991611582 @default.
- W2091260306 cites W1992886282 @default.
- W2091260306 cites W1994622001 @default.
- W2091260306 cites W2009657940 @default.
- W2091260306 cites W2010578681 @default.
- W2091260306 cites W2012489345 @default.
- W2091260306 cites W2012921244 @default.
- W2091260306 cites W2014573547 @default.
- W2091260306 cites W2015495727 @default.
- W2091260306 cites W2018770868 @default.
- W2091260306 cites W2022673131 @default.
- W2091260306 cites W2030230761 @default.
- W2091260306 cites W2036852578 @default.
- W2091260306 cites W2037019860 @default.
- W2091260306 cites W2041026130 @default.
- W2091260306 cites W2042600879 @default.
- W2091260306 cites W2043089761 @default.
- W2091260306 cites W2044498294 @default.
- W2091260306 cites W2051829517 @default.
- W2091260306 cites W2052398809 @default.
- W2091260306 cites W2062407260 @default.
- W2091260306 cites W2064073510 @default.
- W2091260306 cites W2066263735 @default.
- W2091260306 cites W2067352607 @default.
- W2091260306 cites W2067874287 @default.
- W2091260306 cites W2068162695 @default.
- W2091260306 cites W2068705550 @default.
- W2091260306 cites W2074122116 @default.
- W2091260306 cites W2076765200 @default.
- W2091260306 cites W2078659178 @default.
- W2091260306 cites W2082842831 @default.
- W2091260306 cites W2087912135 @default.
- W2091260306 cites W2093165821 @default.
- W2091260306 cites W2119799400 @default.
- W2091260306 cites W2126111554 @default.
- W2091260306 cites W2127420533 @default.
- W2091260306 cites W2163915409 @default.
- W2091260306 cites W227070568 @default.
- W2091260306 cites W2313092301 @default.
- W2091260306 cites W2329507297 @default.
- W2091260306 cites W232992961 @default.
- W2091260306 cites W2332750645 @default.
- W2091260306 cites W2345626125 @default.
- W2091260306 cites W2949559534 @default.
- W2091260306 cites W2950564939 @default.
- W2091260306 cites W2950947659 @default.
- W2091260306 cites W306613413 @default.
- W2091260306 cites W67969648 @default.
- W2091260306 doi "https://doi.org/10.1016/0168-1176(92)85070-g" @default.
- W2091260306 hasPublicationYear "1992" @default.
- W2091260306 type Work @default.
- W2091260306 sameAs 2091260306 @default.
- W2091260306 citedByCount "23" @default.
- W2091260306 countsByYear W20912603062013 @default.
- W2091260306 countsByYear W20912603062022 @default.
- W2091260306 crossrefType "journal-article" @default.
- W2091260306 hasAuthorship W2091260306A5019090382 @default.
- W2091260306 hasConcept C111806078 @default.
- W2091260306 hasConcept C117633835 @default.
- W2091260306 hasConcept C121332964 @default.
- W2091260306 hasConcept C139066938 @default.
- W2091260306 hasConcept C145148216 @default.
- W2091260306 hasConcept C147368240 @default.
- W2091260306 hasConcept C147597530 @default.
- W2091260306 hasConcept C147789679 @default.
- W2091260306 hasConcept C159467904 @default.
- W2091260306 hasConcept C175689099 @default.
- W2091260306 hasConcept C178790620 @default.
- W2091260306 hasConcept C181500209 @default.
- W2091260306 hasConcept C184779094 @default.
- W2091260306 hasConcept C185592680 @default.
- W2091260306 hasConcept C198291218 @default.
- W2091260306 hasConcept C205759337 @default.
- W2091260306 hasConcept C29563950 @default.
- W2091260306 hasConcept C32909587 @default.
- W2091260306 hasConcept C33062035 @default.
- W2091260306 hasConcept C66594872 @default.
- W2091260306 hasConcept C89464430 @default.