Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091265493> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2091265493 endingPage "1843" @default.
- W2091265493 startingPage "1838" @default.
- W2091265493 abstract "Highly halogenated organic compounds, which include polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins (PCDDs) formed during the synthesis of pentachlorophenol and chlorophenoxy herbicides, are often found as contaminants in less toxic nonaqueous media, such as waste oil, oily sludges, or biosolids. Superoxide is highly reactive with halogenated compounds when both are dissolved in nonaqueous media; however, superoxide is most economically generated in water, where it is unreactive with most organic compounds. Superoxide reactivity was investigated in organic solvent-water systems as a basis for treating halogenated contaminants in less toxic nonaqueous media. Such a process could potentially render a contaminated oil or sludge nonhazardous, providing a mechanism for waste volume reduction. Increasing amounts of water added to acetone and dimethyl sulfoxide systems decreased the activity of superoxide in the solvent, but enough activity remained for effective treatment. Superoxide was then generated in the aqueous phase of two-phase water-organic solvent systems, and significant superoxide activity was achieved in the organic media with the addition of phase transfer catalysts (PTCs) to transfer superoxide into the nonaqueous phase. The results of this research demonstrate that superoxide, which can be generated in water electrochemically or through the catalytic decomposition of peroxygens, has the potential to be transferred to oils, sludges, and other less toxic nonaqueous media to destroy highly refractory contaminants such as PCBs, PCDDs, and other halogenated contaminants." @default.
- W2091265493 created "2016-06-24" @default.
- W2091265493 creator A5026660749 @default.
- W2091265493 creator A5039505081 @default.
- W2091265493 creator A5061543746 @default.
- W2091265493 date "2010-01-07" @default.
- W2091265493 modified "2023-10-13" @default.
- W2091265493 title "Volume Reduction of Nonaqueous Media Contaminated with a Highly Halogenated Model Compound Using Superoxide" @default.
- W2091265493 cites W1505061533 @default.
- W2091265493 cites W1965051751 @default.
- W2091265493 cites W1967827780 @default.
- W2091265493 cites W1972471687 @default.
- W2091265493 cites W1978332715 @default.
- W2091265493 cites W1998067926 @default.
- W2091265493 cites W2021974254 @default.
- W2091265493 cites W2028990231 @default.
- W2091265493 cites W2037703397 @default.
- W2091265493 cites W2045840635 @default.
- W2091265493 cites W2052619132 @default.
- W2091265493 cites W2058615039 @default.
- W2091265493 cites W2058867779 @default.
- W2091265493 cites W2062139934 @default.
- W2091265493 cites W2063355742 @default.
- W2091265493 cites W2063797807 @default.
- W2091265493 cites W2071641589 @default.
- W2091265493 cites W2075171038 @default.
- W2091265493 cites W2080458229 @default.
- W2091265493 cites W2087863568 @default.
- W2091265493 cites W2104137320 @default.
- W2091265493 cites W2113573690 @default.
- W2091265493 cites W2134425895 @default.
- W2091265493 cites W230724304 @default.
- W2091265493 cites W2992033081 @default.
- W2091265493 cites W596695791 @default.
- W2091265493 cites W77941366 @default.
- W2091265493 doi "https://doi.org/10.1021/jf903501c" @default.
- W2091265493 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20055413" @default.
- W2091265493 hasPublicationYear "2010" @default.
- W2091265493 type Work @default.
- W2091265493 sameAs 2091265493 @default.
- W2091265493 citedByCount "7" @default.
- W2091265493 countsByYear W20912654932012 @default.
- W2091265493 countsByYear W20912654932016 @default.
- W2091265493 countsByYear W20912654932019 @default.
- W2091265493 countsByYear W20912654932021 @default.
- W2091265493 countsByYear W20912654932022 @default.
- W2091265493 crossrefType "journal-article" @default.
- W2091265493 hasAuthorship W2091265493A5026660749 @default.
- W2091265493 hasAuthorship W2091265493A5039505081 @default.
- W2091265493 hasAuthorship W2091265493A5061543746 @default.
- W2091265493 hasConcept C107872376 @default.
- W2091265493 hasConcept C178790620 @default.
- W2091265493 hasConcept C181199279 @default.
- W2091265493 hasConcept C185592680 @default.
- W2091265493 hasConcept C2779912340 @default.
- W2091265493 hasConcept C2780471494 @default.
- W2091265493 hasConcept C2780795997 @default.
- W2091265493 hasConceptScore W2091265493C107872376 @default.
- W2091265493 hasConceptScore W2091265493C178790620 @default.
- W2091265493 hasConceptScore W2091265493C181199279 @default.
- W2091265493 hasConceptScore W2091265493C185592680 @default.
- W2091265493 hasConceptScore W2091265493C2779912340 @default.
- W2091265493 hasConceptScore W2091265493C2780471494 @default.
- W2091265493 hasConceptScore W2091265493C2780795997 @default.
- W2091265493 hasIssue "3" @default.
- W2091265493 hasLocation W20912654931 @default.
- W2091265493 hasLocation W20912654932 @default.
- W2091265493 hasOpenAccess W2091265493 @default.
- W2091265493 hasPrimaryLocation W20912654931 @default.
- W2091265493 hasRelatedWork W1976106340 @default.
- W2091265493 hasRelatedWork W1994445105 @default.
- W2091265493 hasRelatedWork W1995407410 @default.
- W2091265493 hasRelatedWork W2015375655 @default.
- W2091265493 hasRelatedWork W2056247183 @default.
- W2091265493 hasRelatedWork W2058605546 @default.
- W2091265493 hasRelatedWork W2080400073 @default.
- W2091265493 hasRelatedWork W2109011016 @default.
- W2091265493 hasRelatedWork W2361705853 @default.
- W2091265493 hasRelatedWork W2888298652 @default.
- W2091265493 hasVolume "58" @default.
- W2091265493 isParatext "false" @default.
- W2091265493 isRetracted "false" @default.
- W2091265493 magId "2091265493" @default.
- W2091265493 workType "article" @default.