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- W2091269255 abstract "The kinetics of the exchange of Ce(III) between unchelated Ce(III) ions and Ce(III) chelates of H4EGTA, H4EEDTA, H4PDTA and H4EDTA have been investigated in ammonium acetate buffer solution at 5°C and an ionic strength of 0·1M, using Ce-144 as a radioactive tracer. The complete rate equation was found to be of the form: Rate = k1L[Ce(III)][CeL−] + k2L[H+][Ce(III)][CeL−] + k3L[H+][CeL−] + k4L[H+]2[CeL−] + k5L[H+]3[CeL−]. The fast rate of exchange at high hydrogen ion concentrations prevented terms in [H+]2 and [H+]3 being observed for all the systems. The formation constants of some protonated cerium polyaminocarboxylic acid chelates were determined potentiometrically." @default.
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- W2091269255 date "1973-08-01" @default.
- W2091269255 modified "2023-09-27" @default.
- W2091269255 title "The kinetics of exchange between cerium(III) ions and cerium polyaminocarboxylic acid chelates" @default.
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- W2091269255 doi "https://doi.org/10.1016/0022-1902(73)80518-4" @default.
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