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- W2091276999 abstract "Sephadex G-25 was used with 0.01 m sodium acetate containing a concentration of 3×10−5m Cu(II) as eluent to establish the molecular-size distribution (MSD) and the Cu complexation of molecular-weight fractions of organic solutes. The appropriateness of this modified gel permeation method for complexometric measurements on soluble humic Substances was investigated employing various types of soil solutions. The presence of Cu in the eluent had an effect on the MSD obtained by elimination of electrostatic repulsion between gel and solutes. No evidence was found that the presence of Cu in the chromatographic system induced aggregation of the organic substances. The Cu-binding capacity of the samples as obtained with this gel permeation method was found to increase linearly over a wide sample concentration range varying from 40–2000 mg C dm−3. No interference was observed between the Cu-complexation by exclusion and inclusion peaks in the chromatograms. The analyses revealed that the fraction apparently low in molecular weight makes a large contribution to the complexation potential of forest soil solutions." @default.
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- W2091276999 date "1993-09-01" @default.
- W2091276999 modified "2023-10-16" @default.
- W2091276999 title "Complexometric gel permeation chromatography of soluble humic substances using Sephadex G-25" @default.
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- W2091276999 doi "https://doi.org/10.1111/j.1365-2389.1993.tb00472.x" @default.
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