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- W2091285153 abstract "A mechanistic study on the enantioselective C−H oxidation of vic-diols with the in-situ-generated dioxirane from the fructose-derived ketone 1 is presented. The asymmetrization of meso-configured and the kinetic resolution of racemic vic-diols 2 afforded the optically active α-hydroxy ketones 3 in opposite configurations with moderate to good ee values. Significant electronic effects on the enantioselectivity of C−H insertion have been observed, which are explained in terms of the hydrogen-bonded transition-state structures for the concerted C−H oxygen insertion." @default.
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- W2091285153 date "1999-09-11" @default.
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- W2091285153 title "Asymmetric C−H Oxidation of <i>vic</i>-Diols to α-Hydroxy Ketones by a Fructose-Derived Dioxirane: Electronic Effects on the Enantioselectivity of Oxygen Transfer" @default.
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- W2091285153 doi "https://doi.org/10.1021/jo9907843" @default.
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