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- W2091288441 abstract "The polynitrosyl molybdenum complexes Mo(NO)3(HSO4)3 and [Mo(NO)4(HSO4)2]HSO4)2 with EtAlCl2 form heterogeneous catalytically active systems for olefin metathesis. The catalytic activity of these systems was determined for metathesis of pent-1-ene and pent-2-ene. The interactions of these precatalysts with EtAlCl2 and other aluminum alkyls (Et3Al and Et2AlCl) was investigated. Both precatalysts with Et3Al and EtAlCl2, respectively, form identical trinitrosyl complexes. However, the products of their reaction with Et2AlCl differ. These products were defined on the basis of IR spectra and elemental analysis." @default.
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- W2091288441 date "1990-03-01" @default.
- W2091288441 modified "2023-10-13" @default.
- W2091288441 title "Polynitrosyl molybdenum complexes as olefin metathesis precatalysts" @default.
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- W2091288441 doi "https://doi.org/10.1016/0304-5102(90)85089-z" @default.
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