FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091293031> ?p ?o ?g. }

• W2091293031 endingPage "2206" @default.
• W2091293031 startingPage "2199" @default.
• W2091293031 abstract "The synthesis and characterization of a family of metallacyclic complexes of palladium, that reported where N-N is a diimine ligand and Ar‘ is a substituted aryl. The complexes were isolated from solutions during the catalytic carbonylation of nitroaromatics using palladium complexes and were proposed to be intermediates in the catalytic process. The X-ray structure determination = 4,4‘-bis-tert-butyl-2,2‘-bipyridyl) was carried out, the complex crystallizing in the triclinic space group P1̄ (C30H37N3O3Pd)2·C3H6O, Z = 2, a = 15.626(4) Å, b = 18.269(6) Å, c = 12.067(3) Å, α = 107.34(2)°, β = 111.53(2)°, γ = 78.81(2)°. The crystal structure contains two molecules in the asymmetric unit which are assembled in a quasi-dimeric form via stacking interactions. The previously assigned metallacyclic structure for these complexes was confirmed. A mechanistic pathway for the carbonylation process implicating a series of metallacycle intermediates is proposed without intervention of a metal−imido intermediate. Thermal decomposition studies of the metallacycle and some trapping experiments are also presented." @default.
• W2091293031 created "2016-06-24" @default.
• W2091293031 creator A5009085745 @default.
• W2091293031 creator A5023327466 @default.
• W2091293031 creator A5051505068 @default.
• W2091293031 creator A5073318588 @default.
• W2091293031 date "1998-05-01" @default.
• W2091293031 modified "2023-10-08" @default.
• W2091293031 title "The Palladium-Catalyzed Carbonylation of Nitrobenzene into Phenyl Isocyanate: The Structural Characterization of a Metallacylic Intermediate" @default.
• W2091293031 cites W1523226838 @default.
• W2091293031 cites W1534102405 @default.
• W2091293031 cites W1970144598 @default.
• W2091293031 cites W1972989105 @default.
• W2091293031 cites W1973666472 @default.
• W2091293031 cites W1988414704 @default.
• W2091293031 cites W1991018449 @default.
• W2091293031 cites W1995216587 @default.
• W2091293031 cites W2001282294 @default.
• W2091293031 cites W2002093241 @default.
• W2091293031 cites W2002918699 @default.
• W2091293031 cites W2004635849 @default.
• W2091293031 cites W2007681604 @default.
• W2091293031 cites W2008855274 @default.
• W2091293031 cites W2009317578 @default.
• W2091293031 cites W2011487555 @default.
• W2091293031 cites W2019407049 @default.
• W2091293031 cites W2023477647 @default.
• W2091293031 cites W2028358519 @default.
• W2091293031 cites W2029322327 @default.
• W2091293031 cites W2036273549 @default.
• W2091293031 cites W2060782992 @default.
• W2091293031 cites W2062129975 @default.
• W2091293031 cites W2067528650 @default.
• W2091293031 cites W2068520801 @default.
• W2091293031 cites W2085914117 @default.
• W2091293031 cites W2142896275 @default.
• W2091293031 cites W2169174766 @default.
• W2091293031 cites W2949400187 @default.
• W2091293031 cites W2949787636 @default.
• W2091293031 cites W2950342165 @default.
• W2091293031 cites W2952029999 @default.
• W2091293031 cites W4249349469 @default.
• W2091293031 cites W597408038 @default.
• W2091293031 doi "https://doi.org/10.1021/om9708485" @default.
• W2091293031 hasPublicationYear "1998" @default.
• W2091293031 type Work @default.
• W2091293031 sameAs 2091293031 @default.
• W2091293031 citedByCount "57" @default.
• W2091293031 countsByYear W20912930312012 @default.
• W2091293031 countsByYear W20912930312013 @default.
• W2091293031 countsByYear W20912930312014 @default.
• W2091293031 countsByYear W20912930312015 @default.
• W2091293031 countsByYear W20912930312016 @default.
• W2091293031 countsByYear W20912930312017 @default.
• W2091293031 countsByYear W20912930312018 @default.
• W2091293031 countsByYear W20912930312019 @default.
• W2091293031 countsByYear W20912930312021 @default.
• W2091293031 countsByYear W20912930312022 @default.
• W2091293031 countsByYear W20912930312023 @default.
• W2091293031 crossrefType "journal-article" @default.
• W2091293031 hasAuthorship W2091293031A5009085745 @default.
• W2091293031 hasAuthorship W2091293031A5023327466 @default.
• W2091293031 hasAuthorship W2091293031A5051505068 @default.
• W2091293031 hasAuthorship W2091293031A5073318588 @default.
• W2091293031 hasConcept C115624301 @default.
• W2091293031 hasConcept C116569031 @default.
• W2091293031 hasConcept C120665830 @default.
• W2091293031 hasConcept C121332964 @default.
• W2091293031 hasConcept C135361552 @default.
• W2091293031 hasConcept C155647269 @default.
• W2091293031 hasConcept C161790260 @default.
• W2091293031 hasConcept C168382676 @default.
• W2091293031 hasConcept C170493617 @default.
• W2091293031 hasConcept C178790620 @default.
• W2091293031 hasConcept C185592680 @default.
• W2091293031 hasConcept C207114421 @default.
• W2091293031 hasConcept C2779578285 @default.
• W2091293031 hasConcept C2780263894 @default.
• W2091293031 hasConcept C2780534471 @default.
• W2091293031 hasConcept C2781076698 @default.
• W2091293031 hasConcept C32909587 @default.
• W2091293031 hasConcept C42228675 @default.
• W2091293031 hasConcept C502130503 @default.
• W2091293031 hasConcept C50515024 @default.
• W2091293031 hasConcept C512735826 @default.
• W2091293031 hasConcept C55493867 @default.
• W2091293031 hasConcept C71240020 @default.
• W2091293031 hasConcept C8010536 @default.
• W2091293031 hasConceptScore W2091293031C115624301 @default.
• W2091293031 hasConceptScore W2091293031C116569031 @default.
• W2091293031 hasConceptScore W2091293031C120665830 @default.
• W2091293031 hasConceptScore W2091293031C121332964 @default.
• W2091293031 hasConceptScore W2091293031C135361552 @default.
• W2091293031 hasConceptScore W2091293031C155647269 @default.
• W2091293031 hasConceptScore W2091293031C161790260 @default.
• W2091293031 hasConceptScore W2091293031C168382676 @default.
• W2091293031 hasConceptScore W2091293031C170493617 @default.
• W2091293031 hasConceptScore W2091293031C178790620 @default.

• next