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- W2091298526 abstract "According to the data of simultaneous gas-phase electron diffraction (GED) and mass spectrometric (MS) experiments the vapour over beryllium dichloride at 547 K consists of monomeric and dimeric molecules in the ratio 97.5:2.5. Molecular parameters were refined for both molecules from GED data. The equilibrium structure of BeCl2 is linear with the bond length ranhe(BeCl) = 1.791(5) Å. The thermal-average bond length rg(BeCl) is 1.798(4) Å. Relations between different kinds of the refined parameters (ra,rα,rhe,rche,ranhe) are discussed. Force constants and vibrational frequencies were obtained for this molecule from GED data alone. Assuming D2h symmetry the following parameters were obtained for Be2Cl4: rg(BeClt = 1.828(14) Å, rg(BeClb = 1.968(20) Å, ∠α(CltBeClb = 134(4)°. The force constants and frequencies for the dimer were estimated." @default.
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- W2091298526 date "1996-10-01" @default.
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- W2091298526 title "Structural investigation of molecules in the vapour over beryllium dichloride using electron diffraction and mass spectrometric data" @default.
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- W2091298526 doi "https://doi.org/10.1016/s0022-2860(96)09333-7" @default.
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