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- W2091309789 abstract "The reorientation of CClF2 groups in N(CH3)4H(ClF2CCOO)2 has been studied using pulsed NQR and NMR techniques. The temperature dependence of both chlorine (35Cl) NQR and fluorine (19F) NMR spin-lattice relaxation has been measured T1Q of chlorine is attributed to the sum of two contributions: the reorientation of CClF2 groups and the modulation of the electric field gradient (EFG) produced by the motion of the N(CH3)4+ cations. The activation energies were determined for both kinds of motion. The fluorine relaxation is dominated by an intramolecular 19F-1H dipolar interaction. In analysis of cross-relaxation effects the spectral density functions have been evaluated using the motional parameters obtained from NQR data." @default.
- W2091309789 created "2016-06-24" @default.
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- W2091309789 date "1996-04-01" @default.
- W2091309789 modified "2023-10-18" @default.
- W2091309789 title "35Cl NQR and 19F NMR relaxation studies of CClF2 group dynamics in N(CH3)4H(ClF2CCOO)2" @default.
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- W2091309789 doi "https://doi.org/10.1016/0926-2040(95)01216-8" @default.
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