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- W2091327573 abstract "Carbon-carbon bond cleavage reactions of organic compounds using transition metal complexes are reviewed. The reactions are first classified by the bond order; (i) carbon-carbon single bond cleavage, (ii) carbon-carbon double bond cleavage, and (iii) carbon-carbon triple bond cleavage. For the carbon-carbon single bond cleavage reactions, reactions are classified by the functional groups of the organic compounds. It is shown that in many cases the β, γ-carbon-carbon bond of the organic molecules on metals tends to be cleaved formally. In the case of the carbon-carbon double bond, there are only some examples of the direct cleavage by metals such as a ketene which produces a carbonyl-carbene complex. The direct cleavage of the double bond by metals, which formally affords bis-carbene, is not favorable. In contrast, the carbon-carbon cleavage of the triple bond is achieved by the multi-metal systems which stabilize the cleaved fragments." @default.
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- W2091327573 date "2003-01-01" @default.
- W2091327573 modified "2023-10-03" @default.
- W2091327573 title "Carbon-Carbon Bond Cleavage Reaction and Its Application Using Transition Metals" @default.
- W2091327573 doi "https://doi.org/10.5059/yukigoseikyokaishi.61.938" @default.
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