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- W2091330885 abstract "The bromine nuclear quadrupole resonance study of indium tribromide has revealed that there are at least two modifications in its solid state. The high-temperature modification shows the two 81Br resonance lines of 85.985 and 86.205 MHz, with the relative intensity of 1 : 2 at 24.5°C. This modification was stable unless the temperature was lowered to ∼15°C. The low-temperature modification shows one 81Br resonance line, 86.915 MHz, at −196°C and was stable up to ∼30°C. The directions of the z axes of the field gradient were determined by studying the Zeeman effect on each resonance line of the two modifications at room temperature. For the two resonance lines of the high-temperature modification, one and two directions, which had the asymmetry parameters of 0.362 and 0.400 respectively, were observed. The resonance line of the low-temperature modification showed three directions with the asymmetry parameter of 0.387. The crystal structures of the high- and low-temperature modifications were, therefore, concluded to be monoclinic and hexagonal respectively, from the numbers of resonance lines and of the nonequivalent directions of the z axes. The quadrupole coupling constants and asymmetry parameters were analyzed by means of the Townes-Dailey method." @default.
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- W2091330885 date "1973-03-01" @default.
- W2091330885 modified "2023-10-04" @default.
- W2091330885 title "The Bromine Nuclear Quadrupole Resonance of Two Modifications of Indium Tribromide" @default.
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- W2091330885 doi "https://doi.org/10.1246/bcsj.46.741" @default.
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