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• W2091341823 endingPage "748" @default.
• W2091341823 startingPage "739" @default.
• W2091341823 abstract "Reactions of bis(pyridin-2-yl)ketone with tin tetrahalides, SnX4 (X = Cl or Br), or organotin trichlorides, R′SnCl3 (R′ = Ph, Bu or CH2CH2CO2Me), in ROH (R = Me or Et) readily produces RObis(pyridin-2-yl)methanolato)tin complexes, [5: RO(py)2C(OSnX3)] (5: R,X = Me,Cl; Et,Cl; Et,Br) or [6: MeO(py)2C(OSnCl2R′)] (R′ = Ph, Bu, CH2CH2CO2Me). In addition, halide exchange reaction between SnI4 and (5: R,X = Me,Cl) occurred to give (5: R,X = Me,I). The crystal structures of six tin(IV) derivatives indicated, in all cases, a monoanionic tridentate ligand, [RO(py)2C(O−)-N,O,N], arranged in a fac manner about a distorted octahedral tin atom. The Sn–O and Sn–N bonds lengths do not show much variation amongst the six complexes despite the differences in the other ligands at tin." @default.
• W2091341823 created "2016-06-24" @default.
• W2091341823 creator A5019486609 @default.
• W2091341823 creator A5040627428 @default.
• W2091341823 creator A5059800318 @default.
• W2091341823 creator A5090341915 @default.
• W2091341823 date "2010-02-01" @default.
• W2091341823 modified "2023-10-09" @default.
• W2091341823 title "Formation and crystal structures of [(alkoxy)bis(pyridin-2-yl)methanolato-N,O,N]tin(IV) complexes" @default.
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• W2091341823 doi "https://doi.org/10.1016/j.poly.2009.10.021" @default.
• W2091341823 hasPublicationYear "2010" @default.
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