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- W2091367775 abstract "Wahrend 1,5-Dihydroxynaphthalin bei der farbstoffsensibilisierten Photooxidation unter Cycloaddition von 1O2 regiospezifisch Juglon (3) in hoher Ausbeute liefert, entstehen unter gleichen Reaktionsbedingungen aus dem Monomethylether 1 die Verbindungen 2, 3 und 4 und aus dem Dimethylether 5 die Verbindungen 2, 6 und 7. Die Etherspaltungen sind nicht das Ergebnis von 1O2-Reaktionen im Sinne einer Cycloaddition, sondern Elektronentransferoxidationen uber Radikalionenpaare mit O2·− als Anionen.1,4-Naphthoquinones, X: Reactions of the Methyl Ethers of 1,5-Dihydroxynaphthalene with Singlet OxygenWhile the cycloaddition of 1O2 in the dye sensitized photooxygenation of 1,5-dihydroxynaphthalene leads to juglone (3) regiospecifically in high yield the monomethyl ether 1 gives 2, 3 and 4 and the dimethyl ether 5 gives 2, 6 and 7. The ether splittings are not the results of 1O2 cycloadditions but of electron transfer oxygenations by way of radical ion pairs with O2·− as the anion." @default.
- W2091367775 created "2016-06-24" @default.
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- W2091367775 date "1985-01-01" @default.
- W2091367775 modified "2023-09-24" @default.
- W2091367775 title "Untersuchungen an 1,4-Naphthochinonen, 10. Mitt. Reaktionen von Methylethern des 1,5-Dihydroxynaphthalins mit Singulettsauerstoff" @default.
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- W2091367775 doi "https://doi.org/10.1002/ardp.19853181014" @default.
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