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- W2091386181 abstract "Novel procedures are developed for the synthesis of highly stable carbon composite catalyst supports (CCCS-800 °C and CCCS-1100 °C) and an activated carbon composite catalyst support (A-CCCS). These supports are synthesized through: (i) surface modification with acids and inclusion of oxygen groups, (ii) metal-catalyzed pyrolysis, and (iii) chemical leaching to remove excess metal used to dope the support. The procedure results in increasing carbon graphitization and inclusion of non-metallic active sites on the support surface. Catalytic activity of CCCS indicates an onset potential of 0.86 V for the oxygen reduction reaction (ORR) with well-defined kinetic and mass-transfer regions and ∼2.5% H2O2 production in rotating ring disk electrode (RRDE) studies. Support stability studies at 1.2 V constant potential holding for 400 h indicate high stability for the 30% Pt/A-CCCS catalyst with a cell potential loss of 27 mV at 800 mA cm−2 under H2-air, 32% mass activity loss, and 30% ECSA loss. Performance evaluation in polymer electrolyte membrane (PEM) fuel cell shows power densities (rated) of 0.18 and 0.23 gPt kW−1 for the 30% Pt/A-CCCS and 30% Pt/CCCS-800 °C catalysts, respectively. The stabilities of various supports developed in this study are compared with those of a commercial Pt/C catalyst." @default.
- W2091386181 created "2016-06-24" @default.
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- W2091386181 date "2015-01-01" @default.
- W2091386181 modified "2023-09-24" @default.
- W2091386181 title "Development of catalytically active and highly stable catalyst supports for polymer electrolyte membrane fuel cells" @default.
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- W2091386181 doi "https://doi.org/10.1016/j.jpowsour.2014.09.142" @default.
- W2091386181 hasPublicationYear "2015" @default.
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