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- W2091451570 abstract "The standard molar Gibbs free energies of formation of Na2Mo2O7(s), Na2Mo3O10(l), and Na2Mo3O6(s) have been determined by setting up galvanic cells using 15 moles per cent calcia-stabilized zirconia (CSZ) electrolyte tubes. The cells werePt|Na2MoO4(s)+Na2Mo2O7(s)+MoO2(s)|CSZ|air|Pt,(I)Pt|Ni(s)+NiO(s)|CSZ|Na2Mo2O7(s,1)+Na2Mo3O10(1)+MoO2(s)|Pt,(II)Pt|Na2MoO4(s)+Na2Mo3O6(s)+MoO2(s)|CSZ|air|Pt.(III)The dependence of e.m.f. E on temperature T for the cells (I), (II), and (III) was given by{E(I)/mV}±2.9=1087.5−0.4834(T/K),(758to843)K,{E(II)/mV}±0.53=358.50−0.3077(T/K),(843to915)K,{E(III)/mV}±0.92=956.1−0.2902(T/K),(858to921)K.From the known ΔfGoms of Na2MoO4(s), MoO2(s), and NiO(s) and the e.m.f.s of cells (I), (II), and (III), ΔfGom(Na2Mo2O7, s, T), ΔfGom(Na2Mo3O10, l, T), and ΔfGom(Na2Mo3O6, s, T) are given by{ΔfGmo(Na2Mo2O7,s,T)/(kJ⋅mol−1)}±37.68=−2218.85+0.5910(T/K),{ΔfGmo(Na2Mo3O10,l,T)/(kJ⋅mol−1)}±37.68=−2955.06+0.7843(T/K),{ΔfGmo(Na2Mo3O6,s,T)/(kJ⋅mol−1)}±37.68=−2211.7+0.5714(T/K).The values of ΔfGom/(kJ·mol−1) at 850 K for Na2Mo2O7(s), Na2Mo3O10(l), and Na2Mo3O6(s) are −(1716.50±37.68), −(2288.41±37.68), and −(1726.01±37.68), respectively." @default.
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- W2091451570 title "Standard molar gibbs free energies of formation of Na2Mo2O7(s), Na2Mo3O10(l), and Na2Mo3O6(s) by solid-oxide-electrolyte galvanic cells" @default.
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- W2091451570 doi "https://doi.org/10.1016/s0021-9614(05)80296-4" @default.
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