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• W2091489076 abstract "We report a new approach for the synthesis of symmetrical oligothiophenes based on a highly efficient palladium-catalyzed Ullmann coupling reaction. This synthetic route enables the simple preparation of substituted oligothiophenes with a wider range of functionalities and in higher yield compared to previously reported syntheses. We demonstrate our procedure by preparing a novel, highly soluble α,ω-substituted sexithiophene, dibutylphosphonate-α-sexithiophene (DBP-α-6T). We present spectroscopic characterization of this compound in solution and solution cast thin films. Thin film transistors (TFTs) fabricated using solution cast thin films of DBP-α-6T as the p-type semiconducting channel have high on/off ratios, demonstrating the utility of this synthetic approach in the preparation of highly pure materials for solution-deposited organic electronic devices." @default.
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• W2091489076 date "2002-03-06" @default.
• W2091489076 modified "2023-09-25" @default.
• W2091489076 title "An Efficient Synthesis of Symmetrical Oligothiophenes: Synthesis and Transport Properties of a Soluble Sexithiophene Derivative" @default.
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• W2091489076 doi "https://doi.org/10.1021/cm011528l" @default.
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