Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091497369> ?p ?o ?g. }
Showing items 1 to 64 of
64
with 100 items per page.
- W2091497369 endingPage "1743" @default.
- W2091497369 startingPage "1735" @default.
- W2091497369 abstract "A number of dithiocarbamate derivatives Ph 2 Te[S 2 CNR 2 ] 2 , where R = Me, Et, and Ph 2 TeCl[S 2 CNR 2 ], where R = Me, Et, i-Pr, have been prepared and characterized initially by analysis and vibrational spectroscopy. Three crystal structures have been completed that allow for comparisons of the effect of the change in the nature of R and of the presence of a chlorine atom. The dithiocarbamate groups are monodentate (or anisobidentate) and the geometry about tellurium is consistently that of a distorted sawhorse structure. Examples of both inter- and intra-molecular Te … S interactions are observed as well as an intêrmolecular Te … Cl interaction. The crystal structures of Ph 2 Te[S 2 CNMe 2 ] 2 1, [Formula: see text]4 and Ph 2 TeCl[S 2 CN(i-Pr) 2 ] 5 were determined. The cell parameters for 1 are a = 20.158(5) Å, b = 8.632(2) Å, c = 12.727(4) Å, β = 92.70(2)°, V = 2212(1) Å 3 , Z = 4, R = 0.0221, and R w = 0.0243; for 4 are a = 11.198(4) Å, b = 13.974(4) Å, c = 13.812(5) Å, α = 99.56(2)°, β = 103.08(3)°, γ = 87.39(3)°, V = 2076(1) Å 3 , Z = 4, R = 0.0363, and R w = 0.0398; and for 5 are a = 12.736(3) Å, b = 8.397(1) Å, c = 21.961(1) Å, β = 117.36(1)°, V = 2086(7) Å 3 , Z = 4, R = 0.0266, and R w = 0.0312. NMR spectra are not simple and indicate that several species are present in solution. Keywords: structure, tellurium, chloro, diphenyl, dialkyldithiocarbamato." @default.
- W2091497369 created "2016-06-24" @default.
- W2091497369 creator A5015254107 @default.
- W2091497369 creator A5027396736 @default.
- W2091497369 creator A5041458037 @default.
- W2091497369 creator A5050288059 @default.
- W2091497369 date "1989-11-01" @default.
- W2091497369 modified "2023-10-18" @default.
- W2091497369 title "Preparation and characterization of diphenylbis(<i>N</i>,<i>N</i>-dialkyldithiocarbamato)tellurium (IV) and chlorodiphenyl(<i>N</i>,<i>N</i>-dialkyldithiocarbamato)tellurium(IV). Crystal structures of Ph<sub>2</sub>Te[S<sub>2</sub>CNMe<sub>2</sub>]<sub>2</sub>, Ph<sub>2</sub>TeCl[S<sub>2</sub>CNEt<sub>2</sub>], and Ph<sub>2</sub>TeCl[S<sub>2</sub>CN(<i>i</i>-Pr)<sub>2</sub>]" @default.
- W2091497369 doi "https://doi.org/10.1139/v89-268" @default.
- W2091497369 hasPublicationYear "1989" @default.
- W2091497369 type Work @default.
- W2091497369 sameAs 2091497369 @default.
- W2091497369 citedByCount "18" @default.
- W2091497369 countsByYear W20914973692022 @default.
- W2091497369 crossrefType "journal-article" @default.
- W2091497369 hasAuthorship W2091497369A5015254107 @default.
- W2091497369 hasAuthorship W2091497369A5027396736 @default.
- W2091497369 hasAuthorship W2091497369A5041458037 @default.
- W2091497369 hasAuthorship W2091497369A5050288059 @default.
- W2091497369 hasBestOaLocation W20914973691 @default.
- W2091497369 hasConcept C115624301 @default.
- W2091497369 hasConcept C153642686 @default.
- W2091497369 hasConcept C178516000 @default.
- W2091497369 hasConcept C178790620 @default.
- W2091497369 hasConcept C179104552 @default.
- W2091497369 hasConcept C185592680 @default.
- W2091497369 hasConcept C2777545050 @default.
- W2091497369 hasConcept C538181303 @default.
- W2091497369 hasConcept C66974803 @default.
- W2091497369 hasConcept C71240020 @default.
- W2091497369 hasConcept C8010536 @default.
- W2091497369 hasConceptScore W2091497369C115624301 @default.
- W2091497369 hasConceptScore W2091497369C153642686 @default.
- W2091497369 hasConceptScore W2091497369C178516000 @default.
- W2091497369 hasConceptScore W2091497369C178790620 @default.
- W2091497369 hasConceptScore W2091497369C179104552 @default.
- W2091497369 hasConceptScore W2091497369C185592680 @default.
- W2091497369 hasConceptScore W2091497369C2777545050 @default.
- W2091497369 hasConceptScore W2091497369C538181303 @default.
- W2091497369 hasConceptScore W2091497369C66974803 @default.
- W2091497369 hasConceptScore W2091497369C71240020 @default.
- W2091497369 hasConceptScore W2091497369C8010536 @default.
- W2091497369 hasIssue "11" @default.
- W2091497369 hasLocation W20914973691 @default.
- W2091497369 hasOpenAccess W2091497369 @default.
- W2091497369 hasPrimaryLocation W20914973691 @default.
- W2091497369 hasRelatedWork W1991636179 @default.
- W2091497369 hasRelatedWork W2041243255 @default.
- W2091497369 hasRelatedWork W2067577555 @default.
- W2091497369 hasRelatedWork W2085046397 @default.
- W2091497369 hasRelatedWork W222767794 @default.
- W2091497369 hasRelatedWork W2386037739 @default.
- W2091497369 hasRelatedWork W2849714439 @default.
- W2091497369 hasRelatedWork W3143661298 @default.
- W2091497369 hasRelatedWork W4239653929 @default.
- W2091497369 hasRelatedWork W2069142924 @default.
- W2091497369 hasVolume "67" @default.
- W2091497369 isParatext "false" @default.
- W2091497369 isRetracted "false" @default.
- W2091497369 magId "2091497369" @default.
- W2091497369 workType "article" @default.