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- W2091534842 abstract "Abstract Chiral biferrocene-based bis(oxazoline) compounds, which have both planar and central chirality, are synthesized. The Cu(I)-complexes of the bis(oxazolinyl)biferrocenes were found to be conformationally flexible and have a wide bite angle (136°) by NMR and molecular modeling studies. The complexes catalyzed the intramolecular cyclopropanation reaction of ene-diazoacetates, and low to moderate enantioselectivities and decreased reactivity were observed, compared to known malonate-derived bis(oxazoline) systems." @default.
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- W2091534842 date "1999-08-01" @default.
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- W2091534842 title "Chiral biferrocene-based bis(oxazolines): Ligands for Cu(I)-catalyzed asymmetric cyclopropanations of ene-diazoacetates" @default.
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- W2091534842 doi "https://doi.org/10.1016/s0040-4020(99)00542-6" @default.
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