FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091579109> ?p ?o ?g. }

• W2091579109 endingPage "5202" @default.
• W2091579109 startingPage "5193" @default.
• W2091579109 abstract "The preparation of new scorpionate ligands in the form of the lithium derivatives [(Li(bdmpzdta)(H(2)O))(4)] (1) [bdmpzdta = bis(3,5-dimethylpyrazol-1-yl)dithioacetate], [Li(bdphpza)(H(2)O)(THF)] (2) [bdphpza = bis(3,5-diphenylpyrazol-1-yl)acetate], and [Li(bdphpzdta)(H(2)O)(THF)] (3) [bdphpzdta = bis(3,5-diphenylpyrazol-1-yl)dithioacetate] has been carried out. Furthermore, a series of titanium complexes has been prepared by reaction of TiCl(4)(THF)(2) with the lithium reagents [(Li(bdmpza)(H(2)O))(4)] (4) [bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate] and 1. Under the appropriate experimental conditions neutral complexes, namely [TiCl(3)(kappa(3)-bdmpza)] (5), [TiCl(3)(kappa(3)-bdmpzdta)] (6), and [TiCl(2)(kappa(2)-bdmpzdta)(2)] (7), and cationic complexes, namely [TiCl(2)(THF)(kappa(3)-bdmpza)]Cl (8) and [TiCl(2)(THF)(kappa(3)-bdmpzdta)]Cl (9), were isolated. Complexes 8 and 9 undergo an interesting nucleophilic THF ring-opening reaction to give the corresponding alkoxide-containing species [TiCl(2)(kappa(3)-bdmpza)(O(CH(2))(4)Cl)] (10) and [TiCl(2)(kappa(3)-bdmpzdta)(O(CH(2))(4)Cl)] (11). A family of alkoxide-containing complexes of general formulas [TiCl(2)(kappa(3)-bdmpza)(OR)] [R = Me (12); R = Et (14); R = (i)Pr (16); R = (t)Bu (18)] and [TiCl(2)(kappa(3)-bdmpzdta)(OR)] [R = Me (13); R = Et (15); R = (i)Pr (17)] was also prepared. The structures of these complexes have been determined by spectroscopic methods, and in addition, the X-ray crystal structures of 3, 7, 10, and 11 were also established." @default.
• W2091579109 created "2016-06-24" @default.
• W2091579109 creator A5010573122 @default.
• W2091579109 creator A5036890138 @default.
• W2091579109 creator A5037645861 @default.
• W2091579109 creator A5038200457 @default.
• W2091579109 creator A5048803040 @default.
• W2091579109 creator A5056691009 @default.
• W2091579109 creator A5062992194 @default.
• W2091579109 creator A5065056434 @default.
• W2091579109 creator A5081833446 @default.
• W2091579109 creator A5088764811 @default.
• W2091579109 date "2002-09-11" @default.
• W2091579109 modified "2023-10-14" @default.
• W2091579109 title "Preparation of New Monoanionic “Scorpionate” Ligands: Synthesis and Structural Characterization of Titanium(IV) Complexes Bearing This Class of Ligand" @default.
• W2091579109 cites W1966099302 @default.
• W2091579109 cites W1966100675 @default.
• W2091579109 cites W1968131637 @default.
• W2091579109 cites W1969867427 @default.
• W2091579109 cites W1970732055 @default.
• W2091579109 cites W1973898190 @default.
• W2091579109 cites W1975500584 @default.
• W2091579109 cites W1977055582 @default.
• W2091579109 cites W1978667956 @default.
• W2091579109 cites W1981433147 @default.
• W2091579109 cites W1983437402 @default.
• W2091579109 cites W1986717466 @default.
• W2091579109 cites W1994173901 @default.
• W2091579109 cites W1994608803 @default.
• W2091579109 cites W1995713751 @default.
• W2091579109 cites W1998327071 @default.
• W2091579109 cites W1999949108 @default.
• W2091579109 cites W2001377955 @default.
• W2091579109 cites W2012512484 @default.
• W2091579109 cites W2014815699 @default.
• W2091579109 cites W2021678831 @default.
• W2091579109 cites W2040309167 @default.
• W2091579109 cites W2047216667 @default.
• W2091579109 cites W2056764281 @default.
• W2091579109 cites W2058037493 @default.
• W2091579109 cites W2058216854 @default.
• W2091579109 cites W2064368852 @default.
• W2091579109 cites W2065166866 @default.
• W2091579109 cites W2068264524 @default.
• W2091579109 cites W2075089839 @default.
• W2091579109 cites W2080713036 @default.
• W2091579109 cites W2081613402 @default.
• W2091579109 cites W2082155912 @default.
• W2091579109 cites W2084635057 @default.
• W2091579109 cites W2089578502 @default.
• W2091579109 cites W2095531445 @default.
• W2091579109 cites W2148066840 @default.
• W2091579109 cites W2149998725 @default.
• W2091579109 cites W2158794084 @default.
• W2091579109 cites W2170380844 @default.
• W2091579109 cites W2316353842 @default.
• W2091579109 cites W3137877282 @default.
• W2091579109 cites W3138730820 @default.
• W2091579109 cites W3195202782 @default.
• W2091579109 doi "https://doi.org/10.1021/ic020319f" @default.
• W2091579109 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12354053" @default.
• W2091579109 hasPublicationYear "2002" @default.
• W2091579109 type Work @default.
• W2091579109 sameAs 2091579109 @default.
• W2091579109 citedByCount "75" @default.
• W2091579109 countsByYear W20915791092012 @default.
• W2091579109 countsByYear W20915791092013 @default.
• W2091579109 countsByYear W20915791092014 @default.
• W2091579109 countsByYear W20915791092015 @default.
• W2091579109 countsByYear W20915791092016 @default.
• W2091579109 countsByYear W20915791092017 @default.
• W2091579109 countsByYear W20915791092019 @default.
• W2091579109 countsByYear W20915791092023 @default.
• W2091579109 crossrefType "journal-article" @default.
• W2091579109 hasAuthorship W2091579109A5010573122 @default.
• W2091579109 hasAuthorship W2091579109A5036890138 @default.
• W2091579109 hasAuthorship W2091579109A5037645861 @default.
• W2091579109 hasAuthorship W2091579109A5038200457 @default.
• W2091579109 hasAuthorship W2091579109A5048803040 @default.
• W2091579109 hasAuthorship W2091579109A5056691009 @default.
• W2091579109 hasAuthorship W2091579109A5062992194 @default.
• W2091579109 hasAuthorship W2091579109A5065056434 @default.
• W2091579109 hasAuthorship W2091579109A5081833446 @default.
• W2091579109 hasAuthorship W2091579109A5088764811 @default.
• W2091579109 hasConcept C116569031 @default.
• W2091579109 hasConcept C134018914 @default.
• W2091579109 hasConcept C155647269 @default.
• W2091579109 hasConcept C161790260 @default.
• W2091579109 hasConcept C170493617 @default.
• W2091579109 hasConcept C178790620 @default.
• W2091579109 hasConcept C178907741 @default.
• W2091579109 hasConcept C183882617 @default.
• W2091579109 hasConcept C185592680 @default.
• W2091579109 hasConcept C188027245 @default.
• W2091579109 hasConcept C2778541603 @default.
• W2091579109 hasConcept C2778839380 @default.
• W2091579109 hasConcept C40875361 @default.
• W2091579109 hasConcept C506065880 @default.

• next