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- W2091601834 abstract "Enyne cycloisomerizations can provide an efficient means for forming carbon-carbon bonds. We describe stereoselectively dichotomous enyne cycloisomerizations, entirely dependent on the selection of catalytic manifold. Ruthenium catalysis provides trans-fused bicyclic systems, whereas palladium catalysis provides the analogous cis-fused bicycles. A number of substrates are investigated, and the outcomes ultimately offer a clear mechanistic rationale for these observations." @default.
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- W2091601834 date "2008-11-08" @default.
- W2091601834 modified "2023-09-25" @default.
- W2091601834 title "Ruthenium- and Palladium-Catalyzed Enyne Cycloisomerizations: Differentially Stereoselective Syntheses of Bicyclic Structures" @default.
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- W2091601834 doi "https://doi.org/10.1021/ja8078835" @default.
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